I've had a look and your html link in your header is fine and all of your css validates. Which version of Dreamweaver are you using? Sometimes when you move stuff around Dreamweaver throws a wobbly on my MX version and does stuff similar to what yours is doing. Try dragging the css file out of the folder it's in (in the Dreamweaver explorer window) and then drag it back. It should then update itself again.
If that doesn't work then delete the link from your template (if you've used one). Then add it in again and it should do the same.
Hope this helps and cheers for the comment about my site =)
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